OXIDATIVE ADDITION OF ORGANIC HALIDES TO (ETA-C5H5)3U(THF) (THF = TETRAHYDROFURAN) - A CONVENIENT NEW SYNTHESIS OF TRISCYCLOPENTADIENYL URANIUM(IV) HYDROCARBYL COMPLEXES

被引:18
作者
VILLIERS, C
EPHRITIKHINE, M
机构
关键词
D O I
10.1016/0022-328X(90)85163-S
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Cp3U(THF) (Cp = η-C5H5; THF = tetrahydrofuran) reacts with organic halides RX to give the equimolecular mixture of the Cp3UX and Cp3UR compounds. The features of the reaction are characteristic of an atom abstraction oxidative addition mechanism. Treatment of Cp3UCl with RX in the presence of sodium amalgam leads to quantitative formation of the Cp3UR complexes. © 1990.
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页码:339 / 342
页数:4
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