OXIDATIVE ADDITION OF ORGANIC HALIDES TO (ETA-C5H5)3U(THF) (THF = TETRAHYDROFURAN) - A CONVENIENT NEW SYNTHESIS OF TRISCYCLOPENTADIENYL URANIUM(IV) HYDROCARBYL COMPLEXES

被引：18

作者：

VILLIERS, C

EPHRITIKHINE, M

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 393卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85163-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cp3U(THF) (Cp = η-C5H5; THF = tetrahydrofuran) reacts with organic halides RX to give the equimolecular mixture of the Cp3UX and Cp3UR compounds. The features of the reaction are characteristic of an atom abstraction oxidative addition mechanism. Treatment of Cp3UCl with RX in the presence of sodium amalgam leads to quantitative formation of the Cp3UR complexes. © 1990.

引用

页码：339 / 342

页数：4

共 13 条

[1] [Anonymous], COMPREHENSIVE ORGANO
[2] CHARACTERIZATION OF THE ANION [(ETA-5-C5H5)3UIII-N-C4H9]- - SYNTHESIS AND CRYSTAL-STRUCTURE OF TRICYCLOPENTADIENYL-NORMAL-BUTYLURANIUM(III) LITHIUM CRYPTATE - [(C5H5)3UC4H9]-[LIC14H28N2O4]+
ARNAUDET, L
CHARPIN, P
FOLCHER, G
LANCE, M
NIERLICH, M
VIGNER, D
[J]. ORGANOMETALLICS, 1986, 5 (02) : 270 - 274
[3] BRANDI G, 1973, INORG CHIM ACTA, V7, P319
[4] REACTIONS OF PENTACYANOCOBALTATE(2) WITH SOME ORGANIC HALIDES
CHOCK, PB
HALPERN, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (03) : 582 - &
[5] EFFIO A, 1979, J AM CHEM SOC, V99, P250
[6] ORGANOLANTHANIDE AND ORGANOACTINIDE OXIDATIVE ADDITIONS EXHIBITING ENHANCED REACTIVITY .5. STOICHIOMETRY, KINETIC, AND MECHANISTIC STUDIES OF (C5ME5)2YBII.OET2 OXIDATIVE-ADDITION REACTIONS AND OF (C5ME5)2YBIIIR (R = R, X) YBIII-GRIGNARD REACTIONS WITH ALKYL AND ARYL HALIDES - EVIDENCE FOR THE DOMINANCE OF INNER-SPHERE MECHANISMS
FINKE, RG
KEENAN, SR
WATSON, PL
[J]. ORGANOMETALLICS, 1989, 8 (02) : 263 - 277
[7] (C5ME5)2UCL.THF OXIDATIVE-ADDITION REACTIONS .2. A KINETIC AND MECHANISTIC STUDY
FINKE, RG
SCHIRALDI, DA
HIROSE, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (07) : 1875 - 1876
[8] (C5ME5)2UCL-TETRAHYDROFURAN - OXIDATIVE-ADDITION AND RELATED REACTIONS
FINKE, RG
HIROSE, Y
GAUGHAN, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (05) : 232 - 234
[9] ANIONIC TRICYCLOPENTADIENYLURANIUM(III) COMPLEXES - CRYSTAL-STRUCTURE OF [CP3UCLUCP3][NA(18-CROWN-6)(THF)2] (CP = ETA-C5H5, THF = TETRAHYDROFURAN)
LEMARECHAL, JF
VILLIERS, C
CHARPIN, P
NIERLICH, M
LANCE, M
VIGNER, J
EPHRITIKHINE, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (03) : 259 - 269
[10] SYNTHESIS, CHEMISTRY, AND SPECTROSCOPY OF SOME TRIS(PENTAHAPTOCYCLOPENTADIENYL)URANIUM(IV) ALKYL AND ARYL COMPOUNDS
MARKS, TJ
SEYAM, AM
KOLB, JR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (17) : 5529 - 5539

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