ELECTROCHEMICAL REDUCTION AND STRUCTURAL-PROPERTIES OF BORYLPHOSPHINOETHENE DERIVATIVES

被引：1

作者：

TROEPOLSKAYA, TV

ERMOLAEVA, LV

VAGINA, GA

BALUEVA, AS

ERASTOV, OA

机构：

[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 01期

关键词：

D O I：

10.1007/BF00962994

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intramolecular coordination bonds between phosphoryl-, thio-, and selenophosphoryl groups and boron facilitate the electrochemical reduction of borylphosphinoethene derivatives as compared with their noncyclic analogs. In 1-dibutylboryl-2-diphenylphosphino-1-butyl-2-phenylethene reception of the first electron takes place in the C=C bond. In the oxide, sulfide, and selenide, the electron-accepting centers are most likely the P-C1 and P=R (R=S, Se) bonds. © 1990 Plenum Publishing Corporation.

引用

页码：17 / 20

页数：4

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