THERMAL AND PHYSICAL-PROPERTIES OF THE METHANOL LITHIUM BROMIDE ZINC-CHLORIDE SYSTEM

被引:9
作者
IYOKI, S
TAKIGAWA, T
UEMURA, T
机构
[1] Faculty of Engineering, Kansai University, Suita, Osaka, 564, Yamate-cho
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 1991年 / 14卷 / 02期
关键词
ABSORPTION REFRIGERATING MACHINE; ABSORPTION HEAT PUMP; ABSORPTION HEAT TRANSFORMER; METHANOL-LITHIUM BROMIDE-ZINC CHLORIDE SYSTEM;
D O I
10.1016/0140-7007(91)90079-V
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal properties (heat capacity and heat of mixing) and physical properties (vapour pressure, density, viscosity, surface tension and solubility) of the methanol-lithium bromide-zinc chloride system (1:1 LiBr:ZnCl2 by mass) were measured. The measurements of heat capacity, vapour pressure, density, viscosity and surface tension were carried out at various temperatures and absorbent concentrations. The solubility data were obtained in the temperature range 265.85-343.35 K. The heats of mixing at 298.15 K were obtained for solutions with absorbent concentrations from 0 to 65.8 wt%. Empirical formulae for the heat capacity and the solubility of this system were obtained from experimental data. The vapour pressure data were correlated by an Antoine-type equation. The integral heat of mixing data were correlated by a Redlich-Kister-type equation. Enthalpy-concentration charts for the liquid and vapour phases of this system were constructed on the basis of the observed data.
引用
收藏
页码:78 / 85
页数:8
相关论文
共 15 条
[1]  
Uemura, Hasaba, Investigation of absorption refrigerating machine operating on solution of methanol and lithium bromide, Reito, 43, pp. 784-797, (1968)
[2]  
Hasaba, Uemura, Studies on the methanol-lithium bromide-zinc bromide absorption refrigerating machine, Reito, 44, pp. 720-730, (1969)
[3]  
Uemura, Studies on the methanol-lithium iodide-zinc bromide absorption refrigerating machine, Reito, 50, pp. 95-101, (1975)
[4]  
Aker, Squires, Albright, An evaluation of alcohol-salt mixtures as absorption refrigeration solutions, ASHRAE Trans, 71, pp. 14-20, (1965)
[5]  
Renz, Thermodynamic characteristics of the ternary substance system methanol-lithium bromide-zinc bromide, Klima-Kälte-Heizung, 9, pp. 411-414, (1981)
[6]  
Renz, Steimle, Thermodynamic properties of the binary system
[7]  
methanol-lithium bromide, Int J Refrig, 4, pp. 97-101, (1981)
[8]  
Takagi, Teiryo bunseki no jikken to keisan, (1976)
[9]  
Ueno, Kireito tekiteihou, (1976)
[10]  
Kagaku, Kisohen II, (1984)