SUBSTITUTED QUINONE SYNTHESIS BY PALLADIUM COPPER COCATALYZED CROSS-COUPLING OF STANNYLQUINONES WITH ARYL AND HETEROARYL IODIDES

被引：68

作者：

LIEBESKIND, LS

RIESINGER, SW

机构：

[1] Department of Chemistry, Emory University, Atlanta

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 02期

关键词：

D O I：

10.1021/jo00054a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general and high-yielding route to a variety of aryl- and heteroaryl-substituted quinones is now available via the palladium-copper cocatalyzed cross-coupling of stannylquinones with aryl and heteroaryl iodides. Using this technology a number of novel aromatic- and heteroaromatic-substituted quinones were produced. Mechanistic insight is presented into the various catalytic systems used.

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页码：408 / 413

页数：6

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