DILITHIATED AMINOALCOHOLS AS HOMOCHIRAL BASES

被引：46

作者：

MILNE, D ^{[1
]}

MURPHY, PJ ^{[1
]}

机构：

[1] UNIV WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 10期

关键词：

D O I：

10.1039/c39930000884

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dilithium salts of (+)- or (-)-norephidrine effect the enantioselective and enantiodivergent deprotonation of meso-epoxide 17 in higher enantiomeric excess than previously reported.

引用

页码：884 / 886

页数：3

共 6 条

[1] AN ASYMMETRIC-SYNTHESIS OF CIS-4-TERT-BUTYLDIMETHYLSILOXY-2-CYCLOPENTEN-1-OL AND CIS-4-TETRAHYDROPYRANYLOXY-2-CYCLOPENTEN-1-OL, VERSATILE CHIRAL SYNTHETIC INTERMEDIATE FOR PROSTANOIDS
ASAMI, M
[J]. TETRAHEDRON LETTERS, 1985, 26 (47) : 5803 - 5806
[2] ASYMMETRIC-SYNTHESIS USING HOMOCHIRAL LITHIUM AMIDE BASES
COX, PJ
SIMPKINS, NS
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (01) : 1 - 26
[3] PREPARATION OF PROLINE DERIVED LITHIUM AMIDE BASES AND THEIR USE IN ENANTIOSELECTIVE DEPROTONATION OF MESO EPOXIDES
HENDRIE, SK
LEONARD, J
[J]. TETRAHEDRON, 1987, 43 (14) : 3289 - 3294
[4] FACILE ISOMERIZATION OF OXIRANES TO ALLYL ALCOHOLS BY MIXED METAL BASES
MORDINI, A
RAYANA, EB
MARGOT, C
SCHLOSSER, M
[J]. TETRAHEDRON, 1990, 46 (07) : 2401 - 2410
[5] STEREOSELECTIVE ADDITIONS TO CARBOXYLIC-ACID DIANIONS AND BETA-LACTONE SUBSTITUTED ESTER ENOLATES - APPLICATION TO THE SYNTHESIS OF RACEMIC EPI-BLASTMYCINONE, DELTA-MULTISTRIATINE, PARACONIC ESTERS AND LIGNAN-TYPE DILACTONES
MULZER, J
DELASALLE, P
CHUCHOLOWSKI, A
BLASCHEK, U
BRUNTRUP, G
HUTTNER, G
[J]. TETRAHEDRON, 1984, 40 (12) : 2211 - 2218
[6] VADECARD J, 1993, J CHEM SOC CHEM COMM, V116

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