FRIEDEL-CRAFTS ACYLATIONS WITH MODIFIED CLAYS AS CATALYSTS

被引：93

作者：

CORNELIS, A ^{[1
]}

GERSTMANS, A ^{[1
]}

LASZLO, P ^{[1
]}

MATHY, A ^{[1
]}

ZIEBA, I ^{[1
]}

机构：

[1] ECOLE POLYTECH,F-91128 PALAISEAU,FRANCE

来源：

CATALYSIS LETTERS | 1990年 / 6卷 / 01期

关键词：

environmental compatibility; heterogeneous catalysis; Montmorillonite clay; supported zinc chloride;

D O I：

10.1007/BF00764059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Friedel-Crafts acylations are very effectively catalyzed by clays modified through exchange of the interlamellar cations or through impregnation of metal chlorides. The acidic K10 montmorillonite exchanged with iron(III) gives outstanding results in quantitative (98-100%) acylation of anisole (15 min), mesitylene (15 min), and p-xylene (3 h) at 140-160 °C. Clays impregnated with zinc chloride, such as the K10 montmorillonite, or Japanese acidic clay show near-equivalent catalytic performance. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：103 / 110

页数：8

共 7 条

[1]

[Anonymous], 1973, FRIEDEL CRAFTS CHEM

[2] MONTMORILLONITE SUPPORTED TRANSITION-METAL SALTS AS FRIEDEL-CRAFTS ALKYLATION CATALYSTS [J].