On the Theory of Strong Electrolyte Solutions

被引：213

作者：

Kirkwood, John G. ^{[1
]}

机构：

[1] MIT, Res Lab Phys Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1934年 / 2卷 / 11期

关键词：

D O I：

10.1063/1.1749393

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nature of the approximations involved in the derivation of the Poisson-Boltzmann equation of the Debye-Huckel theory is investigated in detail from the standpoint of classical statistical mechanics. The validity of the initial Debye approximation, under the restrictions originally imposed upon it, is confirmed. Deviations arising from fluctuation terms and van der Waals forces are roughly estimated. An alternative to the Bjerrum method for the treatment of ions of small size and high valence is outlined.

引用

页数：15