NEW SOLVATING CROSS-LINKED POLYETHER FOR LITHIUM BATTERIES

被引：20

作者：

ALLOIN, F

SANCHEZ, JY

ARMAND, M

机构：

[1] Laboratoire d'Ionique et d'Electrochimie des Solides, Domaine Universitaire, 38402 Saint-Martin-d'Heres Cedex

来源：

JOURNAL OF POWER SOURCES | 1995年 / 54卷 / 01期

关键词：

POLYCONDENSATION; POLYMER ELECTROLYTES; IONIC CONDUCTIVITY; POLY(OXYETHYLENE) NETWORK; LITHIUM BATTERIES;

D O I：

10.1016/0378-7753(94)02036-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new attractive polycondensation provides cross-linked solvating polyethers. The electrolytes prepared from these networks exhibit good ionic conductivities from ambient temperature. Their thermal and electrochemical behaviour allow their use in lithium batteries. A comparison between the conductivities of lithium, sodium and potassium network electrolytes shows that lithium electrolytes are more conductive at high concentration while for O/M>20 potassium electrolytes exhibits the best conductivity.

引用

页码：34 / 39

页数：6

共 22 条

[1] ELECTROCHEMICAL-BEHAVIOR OF LITHIUM ELECTROLYTES BASED ON NEW POLYETHER NETWORKS [J].

ALLOIN, F ;

SANCHEZ, JY ;

ARMAND, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) :1915-1920

[2] TRIBLOCK COPOLYMERS AND NETWORKS INCORPORATING OLIGO (OXYETHYLENE) CHAINS [J].

ALLOIN, F ;

SANCHEZ, JY ;

ARMAND, M .

SOLID STATE IONICS, 1993, 60 (1-3) :3-9

[3]

ANDERSON AT, 1992, ELECTROCHIM ACTA, V37, P1539

[4] POLYMER ELECTROLYTES BASED ON POLY-PHOSPHAZENE WITH PENDANT 12-CROWN-4 GROUPS AND MONOVALENT SALTS [J].

ANDREI, M ;

COWIE, JMG ;

PROSPERI, P .

ELECTROCHIMICA ACTA, 1992, 37 (09) :1545-1549

[5]

ARMAND M, 1988, SOLIDS HIGH CONDUCTI

[6] IONIC CONDUCTIVITIES OF POLY(METHOXY POLYETHYLENE-GLYCOL MONOMETHACRYLATE) COMPLEXES WITH LISO3CH3 [J].

BANNISTER, DJ ;

DAVIES, GR ;

WARD, IM ;

MCINTYRE, JE .

POLYMER, 1984, 25 (11) :1600-1602

[7] MICROSCOPIC INVESTIGATION OF IONIC-CONDUCTIVITY IN ALKALI-METAL SALTS POLY(ETHYLENE OXIDE) ADDUCTS [J].

BERTHIER, C ;

GORECKI, W ;

MINIER, M ;

ARMAND, MB ;

CHABAGNO, JM ;

RIGAUD, P .

SOLID STATE IONICS, 1983, 11 (01) :91-95

[8]

BLONSKY PM, 1984, J AM CHEM SOC, V106, P6854, DOI 10.1021/ja00334a071

[9]

CHERADAME H, 1987, POLYM ELECTROLYTE RE, V1, P103

[10]

CHOQUETTE Y, 1992, 6TH INT M LITH BATT

← 1 2 3 →