THERMODYNAMIC PROPERTIES OF SYSTEM CARBON TETRACHLORIDE-TETRACHLOROETHYLENE

被引：9

作者：

FRIED, V

FRANCESC.DR

GALLANTE.AS

机构：

[1] Department of Chemistry, Brooklyn College, City University of New York, Brooklyn

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 05期

关键词：

D O I：

10.1021/j100725a050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have proved experimentally that the system carbon tetrachloride-tetrachloroethylene is nearly ideal. The equilibrium pressure as a function of the mole fraction of carbon tetrachloride, x, is given by P + 144.4 + 476.6x at 70° and P = 95.1 + 348.3x at 60°. Similarly, the molar volume is expressed by V = 102.731 - 5.611x. This indicates that the interaction energy between unlike molecules is the arithmetic mean of the interaction energies for like molecules.

引用

页码：1476 / &

共 21 条

[1] SPECTROSCOPIC EVIDENCE FOR COMPLEX FORMATION BETWEEN CARBON TETRACHLORIDE AND AROMATIC HYDROCARBONS [J].