SYNTHESIS AND REACTIVITY OF A NEUTRAL TUNGSTEN(0) ALKYL COMPLEX - INSERTION OF CO2 INTO THE W-CH3 BOND OF TRANS, TRANS-W(CH3)(CO)2(NO)(PPH3)2 AND THE STRUCTURAL CHARACTERIZATION OF TRANS-W (ETA-2-O2CCH3)(CO)(NO)(PPH3)2

被引：21

作者：

HOLL, MM

HILLHOUSE, GL

FOLTING, K

HUFFMAN, JC

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

[2] INDIANA UNIV,DEPT CHEM,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ORGANOMETALLICS | 1987年 / 6卷 / 07期

关键词：

D O I：

10.1021/om00150a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1522 / 1527

页数：6

共 29 条

[1]

Alexander J. J., 1985, CHEM METAL CARBON BO, V2, P339

[2] PREPARATION AND REACTIONS OF ALKYLPENTACARBONYLTUNGSTEN AND ARYLPENTACARBONYLTUNGSTEN ANIONS [J].

CASEY, CP ;

POLICHNOWSKI, SW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) :7565-7568

[3]

CASEY CP, 1975, J AM CHEM SOC, V97, P7575

[4] HYDROXY-CARBENE DINITROGEN COMPLEX OF RHENIUM [J].

CHATT, J ;

LEIGH, GJ ;

PICKETT, CJ ;

STANLEY, DR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 184 (03) :C64-C66

[5] A KINETIC INVESTIGATION OF CARBON-DIOXIDE INSERTION PROCESSES INVOLVING ANIONIC TUNGSTEN ALKYL AND TUNGSTEN ARYL DERIVATIVES - EFFECTS OF CO2 PRESSURE, COUNTERIONS, AND ANCILLARY LIGANDS - COMPARISONS WITH MIGRATORY CARBON-MONOXIDE INSERTION PROCESSES [J].

DARENSBOURG, DJ ;

HANCKEL, RK ;

BAUCH, CG ;

PALA, M ;

SIMMONS, D ;

WHITE, JN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7463-7473

[6]

DARENSBOURG DJ, 1983, ADV ORGANOMET CHEM, V22, P129

[7] ANIONIC GROUP-6B METAL-CARBONYL HYDRIDES AND FORMATES - CHEMISTRY RELEVANT TO CATALYSIS OF THE WATER GAS SHIFT REACTION BY GROUP-6B METAL HEXACARBONYLS [J].

DARENSBOURG, DJ ;

ROKICKI, A .

ORGANOMETALLICS, 1982, 1 (12) :1685-1693

[8] STEREOCHEMICAL STUDIES OF THE CARBON-DIOXIDE INSERTION REACTIONS INTO THE TUNGSTEN ALKYL BOND [J].

DARENSBOURG, DJ ;

GROTSCH, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7473-7476

[9] REACTIONS OF COORDINATED MOLECULES .20. UNEXPECTED ROUTE TO THE PREPARATION OF HYDROXYCARBENOID AND FORMYLRHENIUM(I) HALIDE-COMPLEXES [J].

DARST, KP ;

LUKEHART, CM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 171 (01) :65-71

[10] CHEMISTRY OF METAL-CARBONYL ANIONS .9. SYNTHESES AND PROPERTIES OF ALKYLPENTACARBONYLMETALATE ANIONS OF CHROMIUM AND TUNGSTEN [J].

ELLIS, JE ;

HAGEN, GP .

INORGANIC CHEMISTRY, 1977, 16 (06) :1357-1360

← 1 2 3 →