SATURATED PYRROLIZIDINEDIOLS .2. TOTAL SYNTHESIS AND STEREOCHEMISTRY OF MACRONECINE

被引：27

作者：

AASEN, AJ

CULVENOR, CC

机构：

[1] Division of Applied Chemistry, C.S.I.R.O, Melbourne

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 12期

关键词：

D O I：

10.1021/jo01264a084

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Macronecine has been synthesised by a two-step reduction of 1-carbethoxy-2,3-dioxopyrrolizidine. The preparation and stereochemical definition of the other three diastereoisomers show that macronecine is 2β-hydroxy-1β-hydroxymethyl-8β-pyrrolizidine. © 1969, American Chemical Society. All rights reserved.

引用

页码：4143 / &

共 10 条

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