NEW CHIRAL RUTHENIUM COMPLEXES FOR ASYMMETRIC CATALYTIC HYDROGENATIONS

被引：67

作者：

TAKAYA, H ^{[1
]}

OHTA, T ^{[1
]}

MASHIMA, K ^{[1
]}

NOYORI, R ^{[1
]}

机构：

[1] NAGOYA UNIV,FAC SCI,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN

来源：

PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期

关键词：

D O I：

10.1351/pac199062061135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New mononuclear complexes, Ru(OCOR)2(binap), and cationic [RuX(binap)(arene)]Y, have been prepared and characterized. These complexes and their derivatives are highly efficient catalysts for asymmetric hydrogenation of enamides, alkyl- and aryl-substituted acrylic acids, (β,ϒ-unsaturated carboxylic acids, allylic and homoallylic alcohols, and a variety of functionalized ketones such asβ-keto esters,α-amino ketones, etc. © 1990 IUPAC

引用

页码：1135 / 1138

页数：4

共 18 条

[1] ASYMMETRIC HYDROGENATION OF TRISUBSTITUTED ACRYLIC ACIDS CATALYZED BY A CHIRAL (AMINOALKYL)FERROCENYLPHOSPHINE RHODIUM COMPLEX [J].

HAYASHI, T ;

KAWAMURA, N ;

ITO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) :7876-7878

[2]

INOUE S, IN PRESS

[3] KINETIC RESOLUTION OF RACEMIC ALLYLIC ALCOHOLS BY BINAP-RUTHENIUM(II)-CATALYZED HYDROGENATION [J].

KITAMURA, M ;

KASAHARA, I ;

MANABE, K ;

NOYORI, R ;

TAKAYA, H .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (03) :708-710

[4] HOMOGENEOUS ASYMMETRIC HYDROGENATION OF FUNCTIONALIZED KETONES [J].

KITAMURA, M ;

OHKUMA, T ;

INOUE, S ;

SAYO, N ;

KUMOBAYASHI, H ;

AKUTAGAWA, S ;

OHTA, T ;

TAKAYA, H ;

NOYORI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) :629-631

[5] GENERAL ASYMMETRIC-SYNTHESIS OF BENZOMORPHANS AND MORPHINANS VIA ENANTIOSELECTIVE HYDROGENATION [J].

KITAMURA, M ;

HSIAO, Y ;

NOYORI, R ;

TAKAYA, H .

TETRAHEDRON LETTERS, 1987, 28 (41) :4829-4832

[6]

MASHIMA K, IN PRESS J CHEM SOC

[7] SYNTHESIS OF 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP), AN ATROPISOMERIC CHIRAL BIS(TRIARYL)PHOSPHINE, AND ITS USE IN THE RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACIDS [J].

MIYASHITA, A ;

YASUDA, A ;

TAKAYA, H ;

TORIUMI, K ;

ITO, T ;

SOUCHI, T ;

NOYORI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (27) :7932-7934

[8] 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) - A NEW ATROPISOMERIC BIS(TRIARYL)PHOSPHINE - SYNTHESIS AND ITS USE IN THE RH(I)-CATALYZED ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACIDS [J].

MIYASHITA, A ;

TAKAYA, H ;

SOUCHI, T ;

NOYORI, R .

TETRAHEDRON, 1984, 40 (08) :1245-1253

[9] ASYMMETRIC-SYNTHESIS OF ISOQUINOLINE ALKALOIDS BY HOMOGENEOUS CATALYSIS [J].

NOYORI, R ;

OHTA, M ;

HSIAO, Y ;

KITAMURA, M ;

OHTA, T ;

TAKAYA, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (22) :7117-7119

[10] ASYMMETRIC HYDROGENATION OF BETA-KETO CARBOXYLIC ESTERS - A PRACTICAL, PURELY CHEMICAL ACCESS TO BETA-HYDROXY ESTERS IN HIGH ENANTIOMERIC PURITY [J].

NOYORI, R ;

OHKUMA, T ;

KITAMURA, M ;

TAKAYA, H ;

SAYO, N ;

KUMOBAYASHI, H ;

AKUTAGAWA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5856-5858

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