SYNTHESIS OF ETHYL ALPHA-CHLORO-(2-F-ALKYLETHYLTHIO)ACETATES FOR PREPARING PRECURSORS OF F-ALKYLATED 2-TAILED SURFACTANTS

被引：4

作者：

DIENG, SY ^{[1
]}

ROMAN, L ^{[1
]}

SZONYI, F ^{[1
]}

CAMBON, A ^{[1
]}

机构：

[1] UNIV NICE,CHIM ORGAN FLUOR LAB,F-06034 NICE,FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)80286-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work we report the synthesis of ethyl alpha-chloro (F-alkyl-2 ethyl thio)acetates (F-alkyl: C4F9-,C6F13-,C8F17-) which are potential synthetic intermediates. We investigated their reactivity with mercaptans and alcohols: the dithioacetal compounds are excellent precursors in the synthesis of double-tailed amphiphiles (25 new compounds were obtained, identified and described).

引用

页码：155 / 164

页数：10

共 11 条

[1]

BERTAINA B, 1985, THESIS U NICE

[2]

BOLLENS E, 1989, FR DEMANDE, V8, P906

[3]

BOLLENS E, 1989, FR DEMANDE, V8, P639

[4] SYNTHESIS AND REACTIVITY OF F-ALKYL SULFIDES AND ACTIVE SULFONES [J].

DIENG, S ;

BERTAINA, B ;

CAMBON, A .

JOURNAL OF FLUORINE CHEMISTRY, 1985, 28 (04) :425-440

[5] FACTORS DETERMINING NUCLEOPHILIC REACTIVITIES [J].

EDWARDS, JO ;

PEARSON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (01) :16-&

[6]

Greenwood F. L., 1963, ORG SYNTH, V4, P108

[7]

SISMONDI A, 1988, FR DEMANDE, V8, P817

[8]

SISMONDI A, 1988, FR DEMANDE, V8, P240

[9]

THORNTON ER, 1964, SOLVOLYSIS MECHANISM, P169

[10]

WILT JW, 1963, ORG SYN COLL, V4, P254

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