A NONAROMATIC EXPANDED PORPHYRIN DERIVED FROM ANTHRACENE - A MACROCYCLE WHICH UNEXPECTEDLY BINDS ANIONS

被引：80

作者：

SESSLER, JL

MODY, TD

FORD, DA

LYNCH, V

机构：

[1] Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期

关键词：

D O I：

10.1002/anie.199204521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chloride receptor in the solid state and an efficient fluoride carrier in solution this describes the anion-binding properties of the diprotonated form of the novel expanded porphyrin 1. This macrocycle is prepared from the condensation of 1,8-diaminoanthracene with the corresponding doubly formyl-substituted tripyrrole. Such macrocycles may serve as models for biological anion-transport systems.

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页码：452 / 455

页数：4

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