A NOVEL CONDUCTING POLYMER FILM BY ELECTROCHEMICAL OXIDATION OF 5-AMINO 2-NAPHTHOL IN ORGANIC AND AQUEOUS-SOLUTIONS

被引：16

作者：

PHAM, MC ^{[1
]}

MOSTEFAI, M ^{[1
]}

LACAZE, PC ^{[1
]}

DAO, LH ^{[1
]}

机构：

[1] INST NATL RECH SCI ENERGIE & MAT,RECH MAT AVANCEES LAB,VARENNES,PQ J3X 1S2,CANADA

来源：

SYNTHETIC METALS | 1994年 / 68卷 / 01期

关键词：

FILM; ELECTROCHEMICAL OXIDATION; 5-AMINO; 2-NAPHTHOL;

D O I：

10.1016/0379-6779(94)90144-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrooxidation of 5-amino 2-naphthol (5-NH2 2-NAP) in acidic aqueous and organic media leads to functionalized polymer film on glassy carbon and Pt electrodes. The electropolymerization occurs via the para-coupling with respect to the -NH2 groups, leading to polyaniline-type film structure containing free -OH groups in the chain. Poly(5-NH2 2-NAP) films prepared in aqueous solution are conducting (sigma similar or equal to 10(-3) S cm(-1)), have long chains (DP similar or equal to 150-220) and show reversible, well-defined redox systems in both acidic organic and aqueous solutions.

引用

页码：39 / 47

页数：9

共 9 条

[1] AN OBSERVATION ON VIBRATIONAL BEHAVIOR OF UNDOPED AND DOPED POLY(ANILINE) PREPARED BY ELECTROCHEMICAL POLYMERIZATION OF ANILINE [J].

BRAHMA, SK .

SOLID STATE COMMUNICATIONS, 1986, 57 (08) :673-675

[2] SURFACE DERIVATIZATION OF HYDROXYL FUNCTIONAL ACRYLIC COPOLYMERS FOR CHARACTERIZATION BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

DICKIE, RA ;

HAMMOND, JS ;

DEVRIES, JE ;

HOLUBKA, JW .

ANALYTICAL CHEMISTRY, 1982, 54 (12) :2045-2049

[3]

DILKS A, 1981, ELECTRON SPECTROSCOP, V4

[4] INSITU INVESTIGATION OF THE FILM GROWTH-MECHANISM USING MULTIPLE INTERNAL-REFLECTION FOURIER-TRANSFORM INFRARED-SPECTROSCOPY (MIRFTIRS) .1. BEHAVIOR OF IRON AND PLATINUM-ELECTRODES IN ALKALINE METHANOLIC SOLUTIONS [J].

PHAM, MC ;

ADAMI, F ;

LACAZE, PC ;

DOUCET, JP ;

DUBOIS, JE .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 201 (02) :413-421

[5] ELECTROCHEMICAL SYNTHESIS AND STUDY OF POLY(5-AMINO 1-NAPHTHOL) FILM IN AQUEOUS AND ORGANIC MEDIA [J].

PHAM, MC ;

MOSTEFAI, M ;

SIMON, M ;

LACAZE, PC .

SYNTHETIC METALS, 1994, 63 (01) :7-15

[6] A PHOTOELECTRON SPECTROSCOPIC STUDY OF THE ELECTROCHEMICAL PROCESSES IN POLYANILINE [J].

SNAUWAERT, P ;

LAZZARONI, R ;

RIGA, J ;

VERBIST, JJ ;

GONBEAU, D .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (04) :2187-2193

[7]

Socrates G., 1980, INFRARED CHARACTERIS

[8] VIBRATIONAL SPECTRA OF PRIMARY AND SECONDARY ALIPHATIC AMINES [J].

STEWART, JE .

JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (05) :1259-1265

[9] THE SYNTHESIS OF 3-HYDROXY-16-EQUILENONE, A STRUCTURAL ISOMER OF EQUILENIN [J].

WILDS, AL ;

CLOSE, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (12) :3079-3083

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