SYNERGISTIC EXTRACTION STUDIES OF AM(III) AND EU(III) FROM PERCHLORIC-ACID WITH 4-BENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-THIONE (BMPPT) AND TRI-NORMAL-OCTYLPHOSPHINE OXIDE (TOPO) IN BENZENE

被引：19

作者：

SMITH, BF

JARVINEN, GD

MILLER, GG

RYAN, RR

PETERSON, EJ

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM,, USA, Los Alamos Natl Lab, Los Alamos, NM, USA

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1987年 / 5卷 / 05期

关键词：

EUROPIUM; -; Extraction; EXTRACTION;

D O I：

10.1080/07366298708918599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The extraction of Am(III) and Eu(III) from aqueous HClO//4 by BMPPT and TOPO in benzene was studied. The ligand BMPPT gave no detectable extraction in the ranges studied, but when BMPPT and TOPO were combined, a synergistic extraction was observed with a selectivity for Am(III) over Eu(III) (K//d//A//m equals 7. 5, Am/Eu equals 68, pH 3. 0, 0. 01 M left bracket TOPO right bracket , 0. 30 M left bracket BMPPT right bracket ).

引用

收藏

页码：895 / 908

页数：14

相关论文

共 28 条

[1] THIOTHENOYLTRIFLUOROACETONE - A NEW CHELON [J].

BERG, EW ;

REED, KP .

ANALYTICA CHIMICA ACTA, 1966, 36 (03) :372-&

[2]

CHOUHAN VS, 1981, P INDIAN AS-CHEM SCI, V90, P317

[3] SOLVENT-EXTRACTION OF COBALT(II), ZINC(II) AND EUROPIUM(III) WITH 4-THIOBENZOYL-2,4-DIHYDRO-5-METHYL-2-PHENYL-3H-PYRAZOL-3-ONE (SBMPP) [J].

CHOUHAN, VS ;

RAO, GN .

JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1979, 52 (01) :199-202

[4] THE SEPARATION OF COBALT-(II), COPPER-(II), ZINC-(II), LEAD-(II), AND CADMIUM-(II) AS THEIR 3-METHYL-1-PHENYL-4-THIOBENZOYL-5-PYRAZOLONE (SBMPP) CHELATES BY THIN-LAYER CHROMATOGRAPHY ON SILICA-GEL [J].

CHOUHAN, VS ;

RAO, GN .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (01) :301-304

[5] METAL COMPLEXES OF THIO-BETA-DIKETONES [J].

COX, M ;

DARKEN, J .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :29-&

[6]

COX M, 1983, HDB SOLVENT EXTRACTI, P53

[7] THE DETERMINATION OF URANIUM BY SOLVENT EXTRACTION .1. THE SEPARATION OF URANIUM-233 FROM IRRADIATED THORIUM AS THE DIETHYLDITHIOCARBAMATE COMPLEX [J].

HARDWICK, WH ;

MORETONSMITH, M .

ANALYST, 1958, 83 (982) :9-13

[8]

HERZSCHUH R, 1983, Z CHEM, V23, P411

[9] ANALYTICAL APPLICATION OF SULFUR ANALOGS OF BETA-DIKETONES .1. EXTRACTION SPECTROPHOTOMETRIC DETERMINATION OF COBALT(II) WITH 1,1,1-TRIFLUORO-4-(2-THIENYL)-4-MERCAPTOBUT-3-EN-2-ONE (STTA) [J].

HONJYO, T ;

KIBA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (01) :185-+

[10] THE EXTRACTION OF SELECTED TRANSPLUTONIUM(III) AND LANTHANIDE(III) IONS BY DIHEXYL-N,N-DIETHYLCARBAMOYLMETHYLPHOSPHONATE FROM AQUEOUS NITRATE MEDIA [J].

HORWITZ, EP ;

MUSCATELLO, AC ;

KALINA, DG ;

KAPLAN, L .

SEPARATION SCIENCE AND TECHNOLOGY, 1981, 16 (04) :417-437