CHEMISTRY OF PYRROLIC COMPOUNDS .8. DIPYRRYLTHIONES

被引：51

作者：

CLEZY, PS

SMYTHE, GA

机构：

[1] Department of Organic Chemistry, University of New South Wales, Kensington, NSW, 2033

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 01期

关键词：

D O I：

10.1071/CH9690239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A number of symmetrical dipyrrylthiones have been prepared by the action of thiophosgene on the appropriate 5-unsubstituted pyrrole. From an examination of their spectroscopic properties it is concluded that these compounds exist predominantly as the thione tautomer. Some chemical properties of the system are described including the conversion of the thiones into ketones by treatment with alkaline peroxide. The mass spectra of dipyrrylthiones and dipyrrylketones are compared. © 1969, CSIRO. All rights reserved.

引用

页码：239 / &

共 22 条

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