PALLADIUM-CATALYZED TANDEM ASSEMBLY OF NORBORNENE, VINYLIC HALIDES, AND CYANIDE NUCLEOPHILE LEADING TO CIS-EXO-2,3-DISUBSTITUTED NORBORNANES

被引：32

作者：

TORII, S

OKUMOTO, H

OZAKI, H

NAKAYASU, S

KOTANI, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, Naka, Okayama

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)98060-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three components, i.e., norbornene, 1-alkenyl or aryl halide, and cyanide nucleophile, were assembled with palladium catalyst (Pd(OAc)2/PPh3) in DMF at 80 °C to obtain stereoselectively cis-exo-2-cyano-3-alkenyl-or arylnorbornanes, which may be prominent intermediates for the currently attractive PGH analogues. © 1990.

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页码：5319 / 5322

页数：4

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