SYNTHESIS OF AROMATIC-COMPOUNDS CONTAINING PERFLUORO-OXA-ALKYL GROUPS

被引：54

作者：

SAWADA, H

NAKAYAMA, M

机构：

[1] Tsukuba Research Laboratory, Nippon Oil and Fats Co., Ltd., Tsukuba-City, Ibaraki, 300-26, Tokodai

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80311-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluoro-oxa-alkanoyl peroxides[[C3F7O(CF(CF3)CF2O)nCF(CF3)CO2]2, n = 0, 1, 2] smoothly reacted with thiophene and furan under mild conditions to affor 2-perfluoro-oxa-alkylthiophenes and furnas in good yields. Perfluoro-oxa-alkylations of benzene and pyrrole were also found to proceed by the use of these peroxides. Furthermore, these peroxides were found to be applied to direct aromatic perfluoro-oxa-alkylations of polystyrene.

引用

页码：117 / 129

页数：13

共 18 条

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