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ISOTOPE AND CENTRIFUGAL COUPLING EFFECTS ON VV AND VT RATE CONSTANTS FOR ENERGY-TRANSFER IN HYDROGEN

被引：2
作者：
CACCIATORE, M
CAPORUSSO, R
BILLING, GD
机构：
[1] UNIV COPENHAGEN,HC ORSTED INST,DEPT CHEM,DK-2100 COPENHAGEN,DENMARK
[2] UNIV BARI,CTR STUDIO CHIM PLASMI,DIPARTIMENTO CHIM,I-70126 BARI,ITALY
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 197卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(92)86028-G
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By using a semi-classical model, which explicitly includes the centrifugal stretch coupling term, for vibrational transitions in diatomic molecules we have investigated the importance of this term. Calculations of VV and VT rates for vibrational transitions in deuterium are compared with experimental data and previous calculations on hydrogen in order to explore isotopic effects.
引用
收藏
页码：92 / 98
页数：7
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