EXTRACTION OF ORGANIC-COMPONENTS FROM AQUEOUS STREAMS BY VACUUM MEMBRANE DISTILLATION

被引:110
作者
SARTI, GC
GOSTOLI, C
BANDINI, S
机构
[1] Dipartimento di Ingegneria Chimica e di Processo, Università degli Studi di Bologna, I-40136 Bologna, Viale Risorgimento
关键词
VACUUM MEMBRANE DISTILLATION; VOLATILE ORGANICS; EVAPORATION; MICROPOROUS MEMBRANES;
D O I
10.1016/0376-7388(93)85129-K
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The removal of volatile organic compounds from aqueous streams by vacuum membrane distillation (VMD) has been analyzed. VMD is an evaporation process which takes place through microporous hydrophobic membranes; at low pressure the mass transfer through the membrane is generally dominated by the Knudsen mechanism, while the process selectivity is essentially determined by the liquid-vapor equilibrium conditions existing at the interface. Dilute aqueous mixtures containing ethanol or methylterbutyl ether have been experimentally investigated, in a wide range of operating conditions. The role of concentration-polarization phenomena on the separation factor was also investigated. A detailed model of the transport phenomena involved in the process is developed and compared with the experimental data. A VMD system is finally designed for the purification of waste waters and the related treatment costs are evaluated.
引用
收藏
页码:21 / 33
页数:13
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