THE STRUCTURE OF R(2)CU(CN)LI-2 LITHIUM CUPRATES - LOWER-ORDER AGGREGATES OF GILMAN REAGENTS AND ORGANOLITHIUM COMPOUNDS

被引：76

作者：

SNYDER, JP

SPANGLER, DP

BEHLING, JR

ROSSITER, BE

机构：

[1] SEARLE RES & DEV,DRUG DESIGN & PROD SYNTH DEV,SKOKIE,IL 60077

[2] BRIGHAM YOUNG UNIV,DEPT CHEM,PROVO,UT 84602

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 10期

关键词：

D O I：

10.1021/jo00089a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A molecular orbital study of lithium cuprates represented by the constitutional formula (CH3)(2)Cu(CN)-Li-2 strongly suggests that the compounds are best described as lower-order Gilman cuprates complexed by ring formation with I mol of either CH3Li or CNLi rather than as tricoordinate Cu(I) ''higher-order'' cyanocuprates.

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页码：2665 / 2667

页数：3

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