METAL TEMPLATED RECEPTORS FOR THE EFFECTIVE COMPLEXATION OF DICARBOXYLATES

被引：69

作者：

GOODMAN, MS ^{[1
]}

JUBIAN, V ^{[1
]}

HAMILTON, AD ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 15期

关键词：

D O I：

10.1016/0040-4039(95)00337-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by H-1 NMR in DMSO and association constants of >10(4) M(-1) were measured in certain cases.

引用

页码：2551 / 2554

页数：4

共 24 条

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