SIMULTANEOUS ELECTROCHEMICAL AND INTERNAL-REFLECTION SPECTROMETRIC MEASUREMENTS USING GOLD-FILM ELECTRODES

被引：46

作者：

PROSTAK, A

MARK, HB

HANSEN, WN

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor

[2] Science Center, Aerospace and Systems Group, North American Rockwell Corporation, Thousand Oaks

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1968年 / 72卷 / 07期

关键词：

D O I：

10.1021/j100853a054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A vacuum-evaporated, uniform, transparent, commercially available thin-film gold electrode is described which permits transmission-like internal-reflection spectra to be obtained during an electrochemical reaction. Optical spectra of eosin Y and tris(4,7-dimethyl-1,10-phenanthroline)iron(II) sulfate are shown and the results are given of measurements made during potentiometric, potential-step, cyclic-voltammetry, and chrono-potentiometric experiments. The results are, with two exceptions, quantitatively understood.

引用

页码：2576 / &

共 32 条

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