DC POLAROGRAPHY - CURRENT-POTENTIAL CURVES FOR ELECTRODE PROCESSES INVOLVING A PRECEDING 1ST-ORDER CHEMICAL-REACTION

被引：24

作者：

GALVEZ, J

SERNA, A

MOLINA, A

MARIN, D

机构：

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 102卷 / 03期

关键词：

D O I：

10.1016/S0022-0728(79)80456-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

An explicit equation, which is valid without any limitation in the magnitude of rate constant of the chemical reaction involved, is derived in a rigorous way, for the d.c. polarographic instantaneous (and average) current-potential curves with a c.e. mechanism accompanied by nernstian behaviour. On the basis of these equations, the range of validity of the steady state approximation is discussed. © 1979 Elsevier Sequoia S.A.

引用

页码：277 / 288

页数：12

共 12 条

[1]

BRINKMAN AAM, 1964, J ELECTROANAL CHEM, V7, P171

[2]

GALVEZ J, 1973, THESIS U MURCIA

[3] *THEORIE LANGSAMER ELEKTRODENREAKTIONEN IN DER POLAROGRAPHIE UND POLAROGRAPHISCHES VERHALTEN EINES SYSTEMS, BEI WELCHEM DER DEPOLARISATOR DURCH EINE SCHNELLE CHEMISCHE REAKTION AUS EINEM ELEKTROINAKTIVEN STOFF ENTSTEHT [J].