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NEW CHEMICAL AND STEREOCHEMICAL APPLICATIONS OF ORGANOIRON COMPLEXES

被引：34
作者：
FATIADI, AJ
机构：
[1] Natl Inst of Standards and, Technology, Gaithersburg, MD
来源：
JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY | 1991年 / 96卷 / 01期
关键词：
APPLICATIONS; ASYMMETRIC SYNTHESIS; CHEMISTRY; CHIRAL AUXILIARIES; ENANTIOMERS; IRON-CARBENE COMPLEXES; ORGANOIRON COMPLEXES; OVERVIEW; IRON IN BIOLOGICAL SYSTEMS; STEREOSELECTIVE REACTIONS;
D O I：
10.6028/jres.096.002
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of alpha, beta-unsaturated acyl ligands bound to the chiral auxiliary [(eta-5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.
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页码：1 / 113
页数：113
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