LASER-INDUCED DECOMPOSITION OF HEPTAFLUORO-2-IODOPROPANE

被引：1

作者：

POLA, J ^{[1
]}

HORAK, M ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CS-18223 PRAGUE 8,CZECHOSLOVAKIA

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1993年 / 58卷 / 01期

关键词：

D O I：

10.1135/cccc19930121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CO2 laser-induced homogeneous decomposition of i-C3F7I yields a variety of perfluorinated compounds, which are suggested to be formed by recombinations of carbenes and radicals generated upon the cleavage of the C-I bond and the fragmentation of the i-C3F7. radical. The decomposition Of i-C3F7I in the presence of ethene leads mainly to the formation of (i-C3F7CH2)2 and i-C3F7(CH2)2I.

引用

页码：121 / 124

页数：4

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