KINETIC ISOTOPE EFFECTS AS A GUIDE TO TRANSITION-STATE GEOMETRIES FOR THE INTRAMOLECULAR COPE AND YLIDE ELIMINATION-REACTIONS - AN AB-INITIO MO STUDY

被引：15

作者：

BACH, RD

GONZALEZ, C

ANDRES, JL

SCHLEGEL, HB

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 14期

关键词：

D O I：

10.1021/jo00119a053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：4653 / 4656

页数：4

共 36 条

[1]

AMOS RD, 1988, CADPAC CAMBRIDGE ANA

[2]

AXELSSON BS, 1989, J AM CHEM SOC, V112, P6661

[3]

Bach R. D., 1972, J AM CHEM SOC, V94, P8608

[4] PRIMARY AND SECONDARY KINETIC ISOTOPE EFFECTS IN THE COPE AND HOFMANN ELIMINATION-REACTIONS [J].

BACH, RD ;

BRADEN, ML .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (26) :7194-7195

[5] NATURE OF THE TRANSITION STRUCTURE FOR OXYGEN ATOM TRANSFER FROM A HYDROPEROXIDE - THEORETICAL COMPARISON BETWEEN WATER OXIDE AND AMMONIA OXIDE [J].

BACH, RD ;

OWENSBY, AL ;

GONZALEZ, C ;

SCHLEGEL, HB ;

MCDOUALL, JJW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) :6001-6011

[6] MECHANISM OF COPE ELIMINATION [J].

BACH, RD ;

ANDRZEJE.D ;

DUSOLD, LR .

JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (09) :1742-1743

[7] ELECTRONIC-STRUCTURE AND REACTIVITY OF DIOXIRANE AND CARBONYL OXIDE [J].

BACH, RD ;

ANDRES, JL ;

OWENSBY, AL ;

SCHLEGEL, HB ;

MCDOUALL, JJW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) :7207-7217

[8] OXIDATION OF AMINES AND SULFIDES WITH HYDROGEN-PEROXIDE AND ALKYL HYDROGEN-PEROXIDE - THE NATURE OF THE OXYGEN-TRANSFER STEP [J].

BACH, RD ;

SU, MD ;

SCHLEGEL, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) :5379-5391

[9] ELIMINATION REACTIONS OF CYCLOOCTYLAMMONIUM SALTS IN LIQUID AMMONIA [J].

BACH, RD ;

ANDRZEJE.D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (25) :7118-&

[10] GENERAL-METHOD FOR DETERMINING KINETIC ISOTOPE EFFECTS THAT UTILIZES ISOTOPICALLY ENGENDERED CHIRALITY [J].

BACH, RD ;

KNIGHT, JW ;

BRADEN, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4712-4714

← 1 2 3 4 →