OBSERVATIONS ON THE UNUSUAL STEREOCHEMISTRY OF THE OXIDATIVE CLEAVAGE OF PALLADIUM CARBON BONDS

被引：32

作者：

ZHU, GX

MA, SM

LU, XY

HUANG, QC

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

[2] BEIJING UNIV,INST PHYS CHEM,BEIJING 100871,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative cleavage of palladium-carbon bonds by CuCl2 occurs with retention of configuration at the carbon atom in the palladium(II)-catalysed cyclization of allylic 2-alkynoates.

引用

页码：271 / 273

页数：3

共 17 条

[1]

AKERMARK B, 1979, J AM CHEM SOC, V101, P2411

[2]

BACKVALL JE, 1977, TETRAHEDRON LETT, P467

[3]

BACKVALL JE, 1980, J AM CHEM SOC, V102, P393

[4] PALLADIUM IN SOME SELECTIVE OXIDATION REACTIONS [J].

BACKVALL, JE .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (09) :335-342

[5] STEREOCHEMISTRY OF CLEAVAGE OF ORGANOMETALLIC COMPLEXES WITH COPPER(II) [J].

BUDNIK, RA ;

KOCHI, JK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 116 (01) :C3-C6

[6]

CLARK D, 1968, DISCUSS FARADAY SOC, V46, P98

[7] INTERNAL INSERTION OF AN OLEFIN INTO A PALLADIUM SIGMA BOND [J].

COULSON, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (01) :200-&

[8] AROMATIC HALOETHYLATION WITH PALLADIUM AND COPPER HALIDES [J].

HECK, RF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) :5538-&

[9]

HECK RF, 1974, ORGANOTRANSITION MET, P110

[10]

HENRY PM, 1974, J ORG CHEM, V39, P387

← 1 2 →