A DRAMATIC CONFORMATIONAL TRANSFORMATION OF A REGIOREGULAR POLYTHIOPHENE VIA A CHEMOSELECTIVE, METAL-ION ASSISTED DECONJUGATION

被引：38

作者：

MCCULLOUGH, RD

WILLIAMS, SP

机构：

[1] Department of Chemistry, Carnegie Mellon Pittsburgh

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 11期

关键词：

D O I：

10.1021/cm00059a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chemoselective response to Pb2+ ions results in the complete removal of the conjugation of a neutral, conjugated polymer, HT-1, in solution. This effect extends to the solid state as is clearly seen by absorption and X-ray spectroscopy studies. Through this response, certain conjugational states are accessible both in solution and in the solid state.

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页码：2001 / &

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