ORDERED MAGNETIC FRUSTRATION .14. THE MAGNETIC-STRUCTURE OF THE TETRAGONAL BRONZE KMNFEF6

被引：17

作者：

LACORRE, P ^{[1
]}

PANNETIER, J ^{[1
]}

FEREY, G ^{[1
]}

机构：

[1] UNIV MAINE,CNRS,FLUORURES LAB,URA 449,F-72017 LE MANS,FRANCE

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 1991年 / 94卷 / 03期

关键词：

D O I：

10.1016/0304-8853(91)90094-Q

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The magnetic structure of the tetragonal bronze-like KMnFeF6 is solved by means of neutron powder diffraction. The structure (space group Pb' a2') consists of a non-collinear arrangement of spins lying in the (a, b) plane of the crystal cell. Spins belonging to triangular platelets adopt a star arrangement very close to the ideal 120-degrees configuration, whereas the arrangement in square platelets is almost exactly antiparallel. The magnetic structure of KMnFeF6 has been successfully simulated with the program MCMAG by assuming isotropic AF interactions between nearest magnetic neighbours (superexchange interactions).

引用

页码：331 / 336

页数：6

共 22 条

[1] MAGNETIC-PROPERTIES OF THE TETRAGONAL PHASE KXMNXFE1-XF3 [J].

BANKS, E ;

SHONE, M ;

WILLIAMSON, RF ;

BOO, WOJ .

INORGANIC CHEMISTRY, 1983, 22 (22) :3339-3342

[2] CRYSTAL-STRUCTURE OF K0.54(MN,FE)F3 AT ROOM-TEMPERATURE [J].

BANKS, E ;

NAKAJIMA, S ;

WILLIAMS, GJB .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (JAN) :46-49

[3]

Bertaut E. F., 1963, SPIN ARRANGEMENTS CR, VIII, P149, DOI 10.1016/B978-0-12-575303-6.50011-7

[4] NONCOLLINEAR SPIN STRUCTURES [J].

COEY, JMD .

CANADIAN JOURNAL OF PHYSICS, 1987, 65 (10) :1210-1232

[5]

Goodenough JB., 1963, MAGNETISM CHEM BOND

[6] CRYSTALLINE-STRUCTURE OF PSEUDOTETRAGONAL BRONZE KO6FEF3 - TRANSITION TETRAGONAL PYROCHLORE FOR KMM'X6 COMPOUNDS [J].

HARDY, AM ;

HARDY, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (AUG15) :1654-1658

[7]

HEWAT AW, 1973, AERER7350 HARW REP

[8] SUPEREXCHANGE INTERACTION AND SYMMETRY PROPERTIES OF ELECTRON ORBITALS [J].

KANAMORI, J .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1959, 10 (2-3) :87-98

[9]

KOESTER L, 1981, SUMMARY NEUTRON SCAT

[10] ORDERED MAGNETIC FRUSTRATION .10. MAGNETIC-STRUCTURE OF ALPHA-KCRF4 AT 1.5-K [J].

LACORRE, P ;

LEBLANC, M ;

PANNETIER, J ;

FEREY, G .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1987, 66 (02) :219-224

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