CAGE ESCAPE AND SPIN REPHASING OF TRIPLET ION-RADICAL PAIRS - TEMPERATURE-VISCOSITY AND MAGNETIC-FIELD EFFECTS IN PHOTO-REDUCTION OF FLUORENONE BY DABCO

被引：41

作者：

PERIASAMY, N ^{[1
]}

LINSCHITZ, H ^{[1
]}

机构：

[1] BRANDEIS UNIV, DEPT CHEM, WALTHAM, MA 02154 USA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)80513-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Weak magnetic fields are found to increase the bulk ion-radical yield from a triplet radical pair, in temperature-viscosity region where cage recombination occurs. The results are consistent with Noyes' theory of geminate reactions and a hyperfine coupling mechanism for spin inversion leading to quenching. © 1979.

引用

页码：281 / 285

页数：5

共 20 条

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