TUNNELING OF HEAVY-PARTICLES IN THE LOW-TEMPERATURE CHEMISTRY

被引：26

作者：

BENDERSKII, VA

GOLDANSKII, VI

机构：

[1] Russian Academy of Sciences, Institute of Chemical Physics, Moscow

来源：

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1080/01442359209353265

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The quantum dynamics of cryochemical solid-state reactions in the region of the low-temperature limit for the rate constant is considered in the framework of multidimensional nuclear tunnelling when low-frequency displacements of heavy particles lead to the formation of reaction complexes with high barrier transparency.

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页码：1 / 70

页数：70

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