POLYNUCLEAR NICKEL(II) COMPLEXES OF N4O2-COMPARTMENTAL AND N4S2-COMPARTMENTAL MACROCYCLES - THE STRUCTURES OF A NI4O4 CUBANE CLUSTER AND THE BINUCLEAR NICKEL(II) COMPLEX OF A BENZENETHIOLATE MACROCYCLE

被引：82

作者：

ATKINS, AJ

BLAKE, AJ

SCHRODER, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 21期

关键词：

D O I：

10.1039/c39930001662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetranuclear cluster [{Ni2(L1)(MeCO2)}2]2+ (L1 = the dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylphenol) shows a distorted Ni4O4 cubane structure consisting of octahedral nickel(II) centres; the structure of the dithiolate analogue [Ni2(L2)](PFG)2.2dmf (L2 = the dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylbenzenethiol; dmf = dimethylformamide) shows square-planar coordination at nickel(II).

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页码：1662 / 1665

页数：4

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