CRYSTAL FIELD IN RARE-EARTH TRICHLORIDES .4. PARAMETER VARIATIONS

被引：88

作者：

CURTIS, MM

NEWMAN, DJ

STEDMAN, GE

机构：

[1] Department of Theoretical Physics, Oxford, Oxford

[2] Department of Physics, Queen Mary College, London

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 03期

关键词：

D O I：

10.1063/1.1671160

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Parameter variations are determined for changes in the ligand coordination angles and distances in Pr3+: LaCl3. Parameters for Sm3+ and Er3+ substituted in LaCl3 are also calculated. These results are used in conjunction with the superposition approximation to discuss the variation of parameters down the rare-earth series in the trichlorides and to predict values of the dynamic orbit-lattice parameters in PrCl3.

引用

页码：1077 / &

共 25 条

[1] CRYSTAL STRUCTURE OF GDCL3 [J].