OXIDATIVE COUPLING OF TOLUENE THROUGH ORGANOMETALLIC INTERMEDIATES

被引：87

作者：

UNGER, MO

FOUTY, RA

机构：

[1] Plastics Department, E. I. du Pont de Nemours and Company, Inc., Wilmington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organomercury compounds have been shown to undergo substitution by palladium salts with subsequent reduction of the paiiadium(II) to palladium(O) and oxidative coupling of the aromatic rings. The system, toluenemercuric acetate-palladium acetate, was investigated in detail. A mechanism is proposed based on the isomer distribution of the bitolyls. © 1969, American Chemical Society. All rights reserved.

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页码：18 / &

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