THERMAL MICHAEL REACTION .2. MANNICH BASE STRUCTURE

被引:18
作者
BUCHANAN, GL
CURRAN, ACW
WALL, RT
机构
[1] Chemistry Department, The University, Glasgow
关键词
D O I
10.1016/S0040-4020(01)83052-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The structures of a number of Mannich bases have been checked by NMR, the deshielding effect of N-protonation being used to identify adjacent protons. Whilst Mannich bases lacking a β-proton can react Michael-wise via a rearrangement, their quaternary methiodides do not. On this evidence, anomalous literature reports can be rationalised. © 1969.
引用
收藏
页码:5503 / &
相关论文
共 25 条