DETERMINATION OF BUTYLTIN, METHYLTIN AND TETRAALKYLTIN IN MARINE FOOD-PRODUCTS WITH GAS-CHROMATOGRAPHY ATOMIC-ABSORPTION SPECTROMETRY

Extraction methods were developed for the determination of butyltin methyltin and tetraakyltin in marine food products. Alkyltins were complexed with either diphenylthiocarbazone (dithizone) or tropolone from enzymatically hydrolyzed samples. Tetraalkyltins were extracted with hexane. Butyl or methyl derivatives of the alkyltins were made by Grignard reaction for analysis by gas chromatography-atomic absorption spectrometry. Many of the examined marine food products contained ppb levels of alkyltins. Tetramethyltin and tetraethyltin levels were less than the method detection limits of 0.8 and 0.7 ng/g (as Sn), respectively.