FLUORINATION OF TETRAIRIDIUM DODECACARBONYL

被引：21

作者：

BREWER, SA ^{[1
]}

HOLLOWAY, JH ^{[1
]}

HOPE, EG ^{[1
]}

WATSON, PG ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Xenon difluoride sequentially fluorinates Ir4(CO)12 dissolved in anhydrous HF yielding initially the novel neutral complexes mer- and fac-Ir(CO)3F3, which are characterised by F-19, C-13 and C-13{F-19} NMR spectroscopies, and finally [XeF][IrF6].

引用

页码：1577 / 1578

页数：2

共 24 条

[1] NOVEL REACTION OF AN IRIDIUM CARBONYL COMPLEX WITH XENON DIFLUORIDE - THE 1ST METAL FLUOROACYL COMPLEX
BLAKE, AJ
COCKMAN, RW
EBSWORTH, EAV
HOLLOWAY, JH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) : 529 - 530
[2] Brewer S.M., UNPUB
[3] RHENIUM CARBONYL FLUORIDES - PREPARATION, CRYSTAL-STRUCTURE, AND SOME PROPERTIES OF HEXACARBONYLRHENIUM(I) MU-FLUORO-BIS[PENTAFLUORORHENATE(V)]
BRUCE, DM
HOLLOWAY, JH
RUSSELL, DR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (12): : 1627 - 1631
[4] RHENIUM CARBONYL FLUORIDES - PREPARATION OF PENTACARBONYLFLUORORHENIUM AND PREPARATION AND CHEMISTRY OF PENTACARBONYLFLUORORHENIUM-RHENIUM PENTAFLUORIDE
BRUCE, DM
HEWITT, AJ
HOLLOWAY, JH
PEACOCK, RD
WILSON, IL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21): : 2230 - 2235
[5] BETA-HYDRIDE ELIMINATION FROM METHOXO VS ETHYL LIGANDS - THERMOLYSIS OF (DPPE)PT(OCH3)2, (DPPE)PT(CH2CH3)(OCH3) AND (DPPE)PT(CH2CH3)2
BRYNDZA, HE
CALABRESE, JC
MARSI, M
ROE, DC
TAM, W
BERCAW, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (16) : 4805 - 4813
[6] COMPLEXES OF IR(III) CONTAINING THE NOVEL SF3 LIGAND
COCKMAN, RW
EBSWORTH, EAV
HOLLOWAY, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) : 2194 - 2195
[7] COCKMAN RW, IN PRESS INORG CHEM
[8] MO2F4(PR3)4 COMPOUNDS AND A COMPARISON OF THEIR PROPERTIES WITH THOSE OF OTHER MO2X4(PR3)4 COMPOUNDS - A NEW SYNTHETIC ROUTE TO METAL FLUORIDES BY THE REACTION OF ALKYL SPECIES WITH OLAH REAGENT
COTTON, FA
WIESINGER, KJ
[J]. INORGANIC CHEMISTRY, 1992, 31 (05) : 920 - 925
[9] BIDODECAHEDRAL COORDINATION GEOMETRY IN A DIMOLYBDENUM TETRAHYDRIDE CONTAINING 3 FLUORIDE BRIDGES - CRYSTAL AND MOLECULAR-STRUCTURE OF [(PMEPH2)3H2MO)2(MU-F)3]BF4
CRABTREE, RH
HLATKY, GG
HOLT, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (25) : 7302 - 7306
[10] PREPARATION OF DIMOLYBDENUM CARBONYL AND DITUNGSTEN CARBONYL-COMPLEXES CONTAINING TRIPLE FLUORO BRIDGES
DAWSON, DM
HENDERSON, RA
HILLS, A
HUGHES, DL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (06): : 973 - 976

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