STEREOSELECTIVE SYNTHESIS OF OPTICALLY-ACTIVE SYN-1,3-DIOLS AND ANTI-1,3-DIOLS BY THE CATALYTIC ALKYLATION OF A BETA-ALKOXY ALDEHYDE

被引：19

作者：

SOAI, K

HATANAKA, T

YAMASHITA, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 13期

关键词：

D O I：

10.1039/c39920000927

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diastereodivergent synthesis of optically active syn- and anti-1,3-diols is achieved by the alkylation of the beta-alkoxy aldehyde 1 with dialkylzinc reagents using chiral catalysts, providing the first example of the syn-selective alkylation of 1.

引用

页码：927 / 929

页数：3

共 11 条

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