FORMATION OF COLLOIDAL TIO2 FROM ORGANOTITANATE SOLUTIONS USED TO PRODUCE CROSS-LINKED POLYMER GELS

被引：11

作者：

KRAMER, J ^{[1
]}

PRUDHOMME, RK ^{[1
]}

WILTZIUS, P ^{[1
]}

机构：

[1] AT&T BELL LABS,MURRAY HILL,NJ 07974

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1987年 / 118卷 / 01期

关键词：

CHEMICAL REACTIONS - Crosslinking - TITANIUM OXIDES;

D O I：

10.1016/0021-9797(87)90459-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study showed that water-aged triethanolamine titanate crosslinking solutions exist not as uniform solutions but as colloidal dispersions. Presumably, the crosslinking reaction between the polymer chains still occurs through an esterification reaction, but rather than the crosslinking site consisting of a single Ti molecule, the crosslinking occurs at the few remaining -Ti(OR) groups on the TiO//2 particle surface. This new understanding of the colloidal nature of these crosslinking systems suggests several new ways of controlling crosslinking kinetics by modifying the sizes of the colloidal crosslinker.

引用

页码：294 / 296

页数：3

共 12 条

[1]

Berne B. J., 1976, DYNAMIC LIGHT SCATTE

[2]

CHATTERJI J, 1981, J PET TECHNOL, V2042

[3]

CONWAY M, 1984, Patent No. 4462917

[4]

CONWAY M, 1980, SPE9334 SOC PETR ENG

[5]

CONWAY M, 1980, SPE9333 SOC PETR ENG

[6]

CRAIGIE LJ, 1983, SPEDOE11635 SOC PET

[7] PHOTOMETER FOR QUASIELASTIC AND CLASSICAL LIGHT-SCATTERING [J].

HALLER, HR ;

DESTOR, C ;

CANNELL, DS .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1983, 54 (08) :973-983

[8]

HOLLENBEAK KH, 1984, Patent No. 4464270

[9]

KEEFER KD, 1984, MATERIALS RES SOC P, V32

[10]

KNOLL S, 1985, SPEDOE13904 SOC PETR

← 1 2 →