BECKMANN REARRANGEMENT OF 1,2,3,8-TETRAHYDRO-1-HYDROXYIMINOCYCLOPENT[A]INDENE AND 1,2,3,4-TETRAHYDRO-1-HYDROXYIMINOFLUORENE

被引：15

作者：

PINDER, RM

机构：

[1] Chemical Defence Experimental Establishment, Salisbury, Wiltshire, Porton Down

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 13期

关键词：

D O I：

10.1039/j39690001690

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Beckmann rearrangement of 1,2,3,8-tetrahydro-1-hydroxyiminocyclopent[a]indene and 1,2,3,4-tetrahydro1-hydroxyiminofluorene under a variety of conditions, and also Schmidt rearrangement of the parent ketones, gave solely the products of alkyl migration, 3,4-dihydro-9H-indeno[2,1-c]pyridin-1 (2H)-one and 3,4,6,10-tetrahydro-indeno[2,1-c]azepin-1 (2H)-one respectively. It is suggested that the rearrangements occur via a non-stereoselective iminium cation.

引用

页码：1690 / &

共 19 条

[1] INDENE SERIES .1. A SYNTHESIS OF 1-2-3-8-TETRAHYDRO-1-KETOCYCLOPENT[A]INDENE [J].