STABLE REDOX AND ELECTRONICALLY CONDUCTING THIN-FILMS CONTAINING FE(BPY)3(2+) BOUND TO 3-SUBSTITUTED POLY(THIOPHENES)

被引：34

作者：

MIRRAZAEI, R ^{[1
]}

PARKER, D ^{[1
]}

MUNRO, HS ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,S RD,DURHAM DH1 3LE,ENGLAND

来源：

SYNTHETIC METALS | 1989年 / 30卷 / 02期

关键词：

Chemical Reactions--Redox;

D O I：

10.1016/0379-6779(89)90796-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The authors prepared electronically-conducting films that were functionalized with a stable, reversible redox center. In particular, systems were sought in which the redox center was conjugated to the electronically-conducting polymer backbone. Thin films of [Fe(2)32+]n were obtained in an analogous manner by cycling the applied potential between 0 and +1.7 v, monitoring the film growth by cyclic voltammetry. Separate redox reactions for Fe2+/Fe3+ oxidation and polythiophene oxidation and reduction are apparent both in the growing film and in the modified electrode.

引用

页码：265 / 269

页数：5

共 16 条

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