HOMOGENEOUS ACTIVATION OF THE C-H BOND IN FORMATES - DECARBONYLATION OF FORMATES TO ALCOHOLS

被引：51

作者：

JENNER, G

NAHMED, EM

LEISMANN, H

机构：

[1] Laboratoire de Piézochimie Organique, Chimie Organique Appliquée (URA CNRS 469), EHICS, 67008 Strasbourg, 1, rue Blaise Pascal

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 387卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)87180-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triruthenium dodecacarbonyl in the presence of a basic phosphine catalyzes the decarbonylation of formates to the corresponding alcohols in high yield and with high selectivity. The reactions involving methyl and ethyl formate require the basic tricyclohexylphosphine. The reaction path is believed to involve oxidative addition of the CH bond to the ruthenium cluster. © 1990.

引用

页码：315 / 321

页数：7

共 25 条

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