THE N-SUBSTITUTION AND N-OXIDATION EFFECTS ON THE C-13 CHEMICAL-SHIFT OF SOME SUBSTITUTED ANILINES

被引:1
作者
HANNA, SY
机构
[1] Department of Chemistry, College of Science, University of Mosul, Mosul
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 10期
关键词
D O I
10.1016/0584-8539(92)80145-M
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The N-substitution and the N-oxidation effects on the carbon-13 chemical shift for all ring carbons of some substituted anilines are discussed. Correlation of the N-substitution effect with substituent constants by means of a linear combination of two empirical parameters, sigma(I) and sigma(R) has been studied. The best correlation was obtained between the N-methylation effect and the substituent constants.
引用
收藏
页码:1397 / 1401
页数:5
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