ISOTOPE SEPARATION WITH THE cw HYDROGEN FLUORIDE LASER

被引:97
作者
Mayer, S. W. [1 ]
Kwok, M. A. [1 ]
Gross, R. W. F. [1 ]
Spencer, D. J. [1 ]
机构
[1] Aerosp Corp, El Segundo, CA 90245 USA
关键词
D O I
10.1063/1.1653291
中图分类号
O59 [应用物理学];
学科分类号
摘要
A cw hydrogen fluoride laser has been used successfully to separate deuterium from hydrogen by specific photocatalysis of the reaction of methanol with bromine. The strong absorption of H3COH was demonstrated for the HF laser lines P-1(5), P-1(6), and P-1(7) while no absorption by deutero-methanol of the HF beam was observed. Excitation of H2COH by the absorbed beam increased the rate of H3COH removal by reaction with bromine. Irradiation, at 90 W for 60 sec, with the cw hydrogen fluoride laser of a 1 : 1 H3COH : D3COD gas mixture in the presence of bromine produced isotope enrichment to greater than 95% D3COD.
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页码:516 / 519
页数:6
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