THE SYNTHESES AND STRUCTURES OF 2 LARGE IODOANTIMONATE ANIONS

被引：19

作者：

CARMALT, CJ

NORMAN, NC

FARRUGIA, LJ

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 17期

关键词：

D O I：

10.1016/S0277-5387(00)84369-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of two iodoantimonate anions are reported, viz. [Sb8I28]4- and [Sb5I18]3- both of which resulted from hydrolysis in reactions between SbI3, AgBF4 and two equivalents of either DMPU or HMPA, respectively. The cations in the former case are [H(DMPU)2]+ and in the latter case are [H(HMPA)2]+, both of which contain O...H...O hydrogen bonds. The structure of a similar cation [H(OPPh3)2]+, as its [ICl4]- salt, is also described.

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页码：2081 / 2090

页数：10

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