INTRAMOLECULAR 1,3-DIPOLAR ADDITIONS IN 4-O-ALLYL PYRANOSIDE-6-NITRONES - AN APPROACH TO CHIRAL PYRANOPYRANS AND PYRANOOXEPANS

被引：38

作者：

COLLINS, PM ^{[1
]}

ASHWOOD, MS ^{[1
]}

EDER, H ^{[1
]}

WRIGHT, SHB ^{[1
]}

KENNEDY, DJ ^{[1
]}

机构：

[1] MERCK SHARP & DOHME LTD, HODDESDON EN11 9BU, HERTS, ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)88914-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of the easily prepared 6-aldehydo-glucopyranoside allyl ether (5) with N-benzylhydroxylarnine gave nitrone (6), which underwent a 1,3-dipolar addition to the 4-O-allyl group giving after deprotection and hydrogenolysis the chiral pyrano-pyran (11) and the pyrano-oxepan (13). © 1990.

引用

页码：2055 / 2058

页数：4

共 14 条

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