A NOVEL REACTION OF ACETANILIDE WITH NITROBENZENE IN DMSO - AN UNUSUAL SOLVENT ASSISTED REGIOSELECTIVE AROMATIC NUCLEOPHILIC-SUBSTITUTION

被引：14

作者：

AYYANGAR, NR

NAIK, SN

SRINIVASAN, KV

机构：

[1] National Chemical Laboratory, Pune

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)94736-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of acetanilide (1) with nitrobenzene (2) in the presence of a base in DMSO yielded p-nitrosodiphenylamine (3) as the major product. This unusual regioselective formation of the deoxygenated product 3 has been rationalized in terms of solvent effects exerted by DMSO. © 1990.

引用

页码：3217 / 3220

页数：4

共 7 条

[1]

AKITOSHI M, 1977, Patent No. 7944611

[2]

Arnett E. M., 1976, ADV PHYS ORG CHEM, V13, P83, DOI DOI 10.1016/S0065-3160(08)60213-0

[3] A NOVEL SYNTHESIS OF UNSYMMETRICAL AZO AROMATICS INACCESSIBLE BY DIAZO-COUPLING REACTION [J].