STRUCTURE OF HO4MO4O11

被引：19

作者：

GOUGEON, P

GALL, P

MCCARLEY, RE

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

[2] US DOE,AMES LAB,AMES,IA 50011

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270191002342

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ho4Mo4O11, M(r) = 1219.47, orthorhombic, Pbam, a = 10.683 (3), b = 15.848 (4), c = 5.6592 (1) angstrom, V = 958.1 (3) angstrom 3, Z = 4, D(x) = 8.453 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 380.3 cm-1, F(000) = 2096, T = 295 K, R = 0.018 for 1534 observed reflections. The title compound constitutes a new structure type containing infinite chains of trans-edge-shared Mo6 octahedra clusters. The latter show a pairwise distortion and are well separated from each other by the Ho3+ cations which are coordinated by seven O atoms forming a monocapped trigonal prism.

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页码：1585 / 1588

页数：4

相关论文

共 22 条

[1] EMPIRICAL PARAMETERS FOR CALCULATING CATION-OXYGEN BOND VALENCES [J].

BROWN, ID ;

WU, KK .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (JUL15) :1957-1959

[2] SYNTHESIS, STRUCTURE AND PROPERTIES OF MN1.5MO8O11, A UNIQUE STRUCTURE TYPE AMONG COMPOUNDS HAVING INFINITE CHAINS OF TRANS-EDGE-SHARED OCTAHEDRAL CLUSTER UNITS [J].

CARLSON, CD ;

BROUGH, LF ;

EDWARDS, PA ;

MCCARLEY, RE .

JOURNAL OF THE LESS-COMMON METALS, 1989, 156 :325-339

[3] PBMO5O8 AND TL0.8SN0.6MO7O11, NOVEL CLUSTERS OF MOLYBDENUM AND THALLIUM [J].

DRONSKOWSKI, R ;

SIMON, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06) :758-760

[4]

GALL P, 1990, UNPUB

[5] STRUCTURE OF NDMO8O14 CONTAINING THE NEW MO8 CLUSTER [J].

GOUGEON, P ;

MCCARLEY, RE .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :241-244

[6] THE SYNTHESIS AND STRUCTURE DETERMINATION FROM POWDER DIFFRACTION DATA OF LAMO5O8 A NEW OXOMOLYBDATE CONTAINING MO10 CLUSTERS [J].

HIBBLE, SJ ;

CHEETHAM, AK ;

BOGLE, ARL ;

WAKERLEY, HR ;

COX, DE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) :3295-3296

[7] CHAINS OF TRANS-EDGE-SHARING MOLYBDENUM OCTAHEDRA - METAL METAL-BONDING IN EXTENDED SYSTEMS [J].

HUGHBANKS, T ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) :3528-3537

[8] SYNTHESIS AND STRUCTURE OF LAMO7.70O14, A NOVEL COMPOUND CONTAINING AN MO8 CLUSTER [J].

LELIGNY, H ;

LEDESERT, M ;

LABBE, P ;

RAVEAU, B ;

MCCARROLL, WH .

JOURNAL OF SOLID STATE CHEMISTRY, 1990, 87 (01) :35-43

[9] SYNTHESIS AND STRUCTURE OF TERNARY MOLYBDENUM OXIDES LIMO8O10 OR ZNMO8O10 MO8O10 HAVING ORTHOGONAL NONINTERSECTING OCTAHEDRAL CLUSTER CHAINS [J].

LII, KH ;

MCCARLEY, RE ;

KIM, S ;

JACOBSON, RA .

JOURNAL OF SOLID STATE CHEMISTRY, 1986, 64 (03) :347-358

[10] THE CRYSTAL-STRUCTURE OF CA16.5MO13.5O40, AN INTERMEDIATE PHASE IN THE TERNARY-SYSTEM CAO-MO-O [J].

LINDBLOM, B ;

STRANDBERG, R .

ACTA CHEMICA SCANDINAVICA, 1989, 43 (09) :825-828